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排序方式: 共有126条查询结果,搜索用时 218 毫秒
1.
Hameed Al‐Attar Aula A Alwattar Athir Haddad Bassil A Abdullah Peter Quayle Stephen G Yeates 《Polymer International》2021,70(1):51-58
In this work we demonstrate, for the first time, the use of polylactic acid (PLA) as a biodegradable host matrix for the construction of the active emissive layer of organic light‐emitting diode (OLED) devices for potential use in bioelectronics. In this preliminary study, we report a robust synthesis of two fluorescent PLA derivatives, pyrene‐PLA ( AH10 ) and perylene‐PLA ( AH11 ). These materials were prepared by the ring opening polymerisation of l ‐lactide with hydroxyalkyl‐pyrene and hydroxyalkyl‐perylene derivatives using 1,8‐diazabicyclo[5.4.0]undec‐7‐ene as catalyst. OLEDs were fabricated from these materials using a simple device architecture involving a solution‐processed single‐emitting layer in the configuration ITO/PEDOT:PSS/PVK:OXD‐7 (35%): AH10 or AH11 (20%)/TPBi/LiF/Al (ITO, indium tin oxide; PEDOT:PSS, poly(3,4‐ethylenedioxythiophene) doped with poly(styrenesulfonic acid); PVK, poly(vinylcarbazole); OXD‐7, (1,3‐phenylene)‐bis‐[5‐(4‐tert‐butylphenyl)‐1,3,4‐oxadiazole]; TPBi, 2,2′,2″‐(1,3,5‐benzenetriyl)tris(1‐phenyl‐1H‐benzimidazole)). The turn‐on voltage for the perylene OLED at 10 cd m–2 was around 6 V with a maximum brightness of 1200 cd m–2 at 13 V. The corresponding external quantum efficiency and device current efficiency were 1.5% and 2.8 cd A–1 respectively. In summary, this study provides proof of principle that OLEDs can be constructed from PLA, a readily available and renewable bio‐source. © 2020 The Authors. Polymer International published by John Wiley & Sons Ltd on behalf of Society of Industrial Chemistry. 相似文献
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Highly soluble perylene diimide derivatives with symmetrical and unsymmetrical secondary, tertiary alkyl side chains were synthesized and their photophysical properties, redox potentials and thermal stabilities were measured and compared with previously reported 1-pentylhexyl substituted swallow-tailed perylene diimide. Diasteroisomers of the novel, unsymmetrical swallow-tailed substituted perylene diimide compound could not be detected using low temperature NMR spectroscopy. The novel dyes were soluble in a range of organic solvents indicating potential for photo-electronic applications and photocatalytic reactions. Two dyes were not only soluble in organic solvents but also showed solubility in aqueous media as the hydrochloride salt, thus offering potential use in biological applications. 相似文献
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《分离科学与技术》2012,47(16):2548-2556
The novel cellulose resin crosslinked with perylene tetracarboxylic diimides 3 was synthesized and its structure was characterized by elemental analysis, Fourier transform infrared (FTIR) spectroscopy, and scanning electronmicroscopy (SEM), etc. Dyes adsorption experiments of polymer 3 suggested that it exhibited excellent adsorption capacities for tested four cationic and anionic dyes [Orange G sodium salt (OG), Brilliant ponceau 5R (BP), Methylene blue (MB), and Crystal violet (CV)]. The adsorption capacities for OG, BP, MB, CV were as high as 1.04, 1.21, 1.14, and 0.96 mmol/g, respectively. The adsorption processes obeyed the pseudo second-order model and followed the Langmuir isotherm equation. The adsorption processes were exothermic and spontaneous. The pH = 2 ? 12 made slight influences on adsorption capacities of polymer 3 for dyes. It was supposed that the adsorption mechanism was not only the electrostatic forces and hydrogen bond but also the π-π stacking interaction playing an important role in the adsorption processes. 相似文献
6.
Panagiotis E. Keivanidis Frédéric Laquai Ian A. Howard Richard H. Friend 《Advanced functional materials》2011,21(8):1355-1363
Herein, we address the reduction in the external quantum efficiency (EQE) of solution‐processed organic photodetectors caused by the room temperature phase demixing of components in the composite material of the photoactive layer. The reduction takes place under ambient conditions and after the completion of device fabrication. As a model system, we study photoactive blend films that consist of the electron acceptor N,N’‐bis(alkyl)‐3,4,9,10‐perylene tetracarboxylic diimide) (PDI) and the electron donor polymer poly(9,9’‐dioctylfluorene‐co‐benzothiadiazole) (F8BT). The ambient ageing of these photoactive layers is a consequence of the PDI component segregation; however, the final PDI domain size remains smaller than the resolution limit of optical microscopy. We find that the photophysical properties of the aged F8BT:PDI layer and the EQE of the aged device are significantly altered. The fabrication of F8BT:PDI layers from solvents of increasing boiling point allows for the spectroscopic monitoring of the ageing‐induced phase segregation (a‐PSG) process. For each solvent used, the extent of a‐PSG is correlated with the PDI dispersion in the F8BT matrix as received immediately after layer deposition. The tendency for room temperature phase demixing becomes stronger as PDI is more finely dispersed in the freshly spun F8BT:PDI layer. The evolution of the room temperature phase segregation of PDI has a negative impact on the photophysical processes that are essential for charge photogeneration in the F8BT:PDI photoactive layer. 相似文献
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Se Hyun Kim Mi Jang Hoichang Yang John E. Anthony Chan Eon Park 《Advanced functional materials》2011,21(12):2198-2207
A chemically coupled polymer layer is introduced onto inorganic oxide dielectrics from a dilute chlorosilane‐terminated polystyrene (PS) solution. As a result of this surface modification, hydrophilic‐oxide dielectrics gain hydrophobic, physicochemically stable properties. On such PS‐coupled SiO2 or AlOx dielectrics, various vacuum‐ and solution‐processable organic semiconductors can develop highly ordered crystalline structures that provide higher field‐effect mobilities (μFETs) than other surface‐modified systems, and negligible hysteresis in organic field‐effect transistors (OFETs). In particular, the use of PS‐coupled AlOx nanodielectrics enables a solution‐processable triethylsilylethynyl anthradithiophene OFET to operate with μFET ~ 1.26 cm2 V?1 s?1 at a gate voltage below –1 V. In addition, a complementary metal‐oxide semiconductor‐like organic inverter with a high voltage gain of approximately 32 was successfully fabricated on a PS‐coupled SiO2 dielectric. 相似文献
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A semi‐core–shell structure of perylene diimide (PDI) self‐assembly coated with TiO2 nanoparticles is constructed, in which nanoscale porous TiO2 shell is formed and PDI self‐assembly presented 1D structure. A full‐spectrum photocatalyst is obtained using this structure to resolve a conundrum—TiO2 does not exhibit visible‐light photocatalytic activity while PDI does not exhibit ultraviolet photocatalytic activity. Furthermore, the synergistic interaction between TiO2 and PDI enables the catalyst to improve its ultraviolet, visible‐light, and full‐spectrum performance. The interaction between TiO2 and PDI leads to formation of some new stacking states along the Π–Π stacking direction and, as a consequence, electron transfer from PDI to TiO2 suppresses the recombination of e?/h+ and thus improves photocatalytic performance. But the stronger interaction in the interface between TiO2 and PDI is not in favor of photocatalytic performance, which leads to rapid charge recombination due to more disordered stacking states. The study provides a theoretical direction for the study of core–shell structures with soft materials as a core, and an idea for efficient utilization of solar energy. 相似文献
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TiO2 thin and thick films promoted with platinum and organic sensitizers including novel perylene diimide dyes (PDI) were prepared
and tested for carbon dioxide reduction with water under visible light. TiO2 films were prepared by a dip coating sol–gel technique. Pt was incorporated on TiO2 surface by wet impregnation [Pt(on).TiO2], or in the TiO2 film [Pt(in).TiO2] by adding the precursor in the sol. When tris (2,2′-bipyridyl) ruthenium(II) chloride hexahydrate was used as sensitizer,
in addition to visible light activity towards methane production, H2 evolution was also observed. Perylene diimide derivatives used in this study have shown light harvesting capability similar
to the tris (2,2′-bipyridyl) ruthenium(II) chloride hexahydrate. 相似文献